Preheat the oven to 350°F (175 ℃). Grease a 9×9 inch light metal baking pan and line it with parchment paper.
In a medium bowl, whisk together the flour, cocoa powder, baking powder, baking soda, and salt. Then set aside the flour mixture.
2 cups (250 g) all-purpose flour, spooned and leveled, 3/4 cup (60 g) Dutch process cocoa powder , 1 1/2 tsp baking powder, 1/4 tsp baking soda, 1/2 tsp salt
To a large bowl add the softened butter and granulated white sugar. Cream together with an electric mixer on high speed for 2 minutes.(If using a stand mixer, use the paddle attachment.) 2 cups (400 g) granulated white sugar, 3/4 cup (168 g) unsalted butter, softened
Then add in the eggs and vanilla and mix on medium speed until pale in color and smooth, about 1 minute.
3 eggs, at room temperature, 1 tsp vanilla
Add in the dry ingredients and buttermilk, mixing on low speed. Mix just until the batter is combined and smooth, scraping the sides of the bowl with a spatula as necessary.
1 1/4 cups (300 ml) buttermilk, at room temperature
Add in the hot coffee and mix on low speed just until dispersed through the batter.
1/2 cup (120 ml) hot coffee
Pour the cake batter into the prepared cake. Bake the cake for 48-52 minutes, or until a toothpick comes out clean from the center of the cake.
Let the cake cool in the pan on a wire rack for 30 minutes, then pull up on the parchment paper to release it from the pan. Let the cake continue cooling on the wire rack until completely cooled.