Preheat oven to 350 degrees.
Add 3 cups of champagne to a large pot. Simmer the champagne on medium-high heat until it has reduced to ½ cup. Let it completely cool before using it in the cake.
Then cream 10 tablespoon of butter and 1 ½ cups of sugar together in a large bowl.
Next add in four egg whites and 1 teaspoon vanilla. Mix until combined.
Then add in the ½ cup of reduced champagne and combine.
In a separate, medium sized bowl, sift 2 ¼ cups of all purpose flour, ½ teaspoon of salt, 1 ½ teaspoon of baking powder and ¼ teaspoon of baking soda together.
Alternate adding 1 cup of buttermilk and the dry ingredients to the wet ingredients a little at a time. Continue until everything is combined together.
Divide the batter evenly between 3 6" greased cake pans.
Bake the cakes at 350 degrees for 31-34 minutes, or until a toothpick comes out clean from the centers.
Let the cakes cool in their pans for five minutes and then transfer them to a cooling rack to finish completely cooling.